Cooling System Operation...a long, long post....sorry
Actually... question about the failed cap. So... normally if I would take the cap off, there would be some pressure in the tank. Lately though... no pressure when I take it off when hot (like a dumbass).
My question to that would be... what is the normal system pressure of the coolant? Is it pressurized to reduce boiling points? (seems logical)
The cooling system pressure (on most cars) will be at or below 15 psi.
Pressurizing the coolant will RAISE it's boiling point.
The fact that it has had a recent head gasket replacement and is now pushing coolant out the reservoir is enough information for me to suspect that you have a small leak in the head gasket, or a small crack in the head.
You likely have a leak and are losing compression from a engine cylinder or exhaust port and into the coolant system.
If you can rig a pressure gage on the cooling system to check what the actual pressures are in the (hot) cooling system, I suspect that your problem and the reason for it will become obvious.
In normal operation of cooling systems with a expansion reservoir.
The system is pressurized because because the natural physical reaction to the coolant being heated is that it will expand.
This expansion cannot be stopped, it's physically impossible, so it must be dealt with or things will break.
This causes the need for additional space in the cooling system for expansion of the liquid.
By holding the coolant under low (cap) pressure, the coolant is allowed it to expand against the small amount of air in the reservoir.
This pushes coolant into the reservoir and causes pressure to rise on the system.
Under normal circumstances, the pressure will not rise high enough to overcome the set pressure limit of the coolant cap, and the coolant is retained in the coolant bottle.
As the engine and coolant cools, the coolant will contract and pull the coolant back into the engine.
This is caused by the vacuum created by contraction of liquid coolant in a small closed cooling system.
This is why pressure caps have a small one way vent that acts as a vacuum break.
This prevents the cooling system from pulling too much vacuum on the cooling system as the coolant cools and retracts it's expansion.
This vacuum can damage components of the cooling system.
If everything is working as designed, the process repeats itself over and over without losing any coolant to the environment.
Older cars that didn't have a expansion reservoir, relied on the air space above the coolant in the top of the radiator (radiator not quite full) to absorb the expansion of the liquid.
That's why the radiator wasn't ever completely full of coolant in these old systems.
As the liquid expanded, the pressure in the system it would occupy the air above the coolant in the top of the radiator.
This would cause a pressure rise in the enclosed system.
If the expansion was too great (too much coolant in system) the pressure increase to the point where the pressure cap would open and and allow just enough liquid to escape to lower the pressure to pressure cap setting, and the liquid loss would stop.
If you took a empty system and completely filled it with coolant, put the pressure cap on and started the engine, it wouldn't be long until you noticed coolant dripping out the overflow on the pressure cap.
This is caused by liquid expansion requiring more space, and making it's own space.
Eventually the pressures would stabilize against the cap setting, and there would be no more loss of coolant.
In Abnormal Operation of a Closed Cooling System with a expansion reservoir.............
Operation that is affected by a problem such as uncontrolled temperature and pressures in the system caused by leaks between the combustion chamber in the engine into the cooling system, and vise versa.
If there is a pressure leak out of the engine cylinder and into the cooling system it severely affects the operation of the system.
This could be through a leak in the head gasket or a leak through a crack in the head or engine block.
If that happens, the pressure in the cooling system cannot be controlled because the combustion chamber pressures are far above the ability of the cooling system to contain the pressure.
This pressure rise happens could begin as soon as you start the engine, or it could take a while as the engine block and head expands allows the leak ( or crack) to open.
At this point, pressure will rise in the cooling system that is far above the ability of the system to contain, and coolant will be forced through the pressure cap and out in the driveway.
As the coolant is leaked out, the temperature on the system will increase to the point to where steam is generated, and pressure climbs quickly.
The leak gets worse, and eventually all of the coolant will be blown out of the engine.
This is where severe engine damage can occur.
I suspect that the reason there is no pressure on your system when you remove the cap is either the system is completely empty, or that the pressure is leaking back into and through the combustion chamber when you turn the engine off.
Have you seen any indication of oil in the cooling system, or water in the engine oil?
Any water (or steam) coming out of the tail pipe when the engine if running?
Have you tried removing the pressure cap before you start the engine (engine cool) to see if any bubbles are being formed in the coolant as the engine warms??
If so, these are the air bubbles that are over-pressurizing your system.
I know that this is a long post, but maybe it will give some people a insight to how their coolant system works, and also give them a place to start trouble shooting.
Hope this helps someone.