As already mentioned, spraying fuel on a warm (when the engine is running) closed valve gives the fuel more time to atomize.
Although 'time' is a rather relative term. It's not 83 times a minute. At 1000 rpm idle, that's 500 combustion events per minute per cylinder (2 complete rotations to complete the 4 stroke cycle), which is 8.3 per second. Rev it up a bit and it really becomes rather meaningless where exactly in the 2 rotations per cylinder firing the injector fires.
I have my 245 wired up sequentially, so with a click or two in Tuner Studio I can change it from batch to sequential, and in sequential mode I can alter the timing of the injection pretty much over the whole 720 degrees. I messed around with that some not long after I got the car running on the new setup (MS3X and coil on plugs and DSM CAS) and really couldn't tell much of a difference even at idle. Might make more of a difference on a cold start, but I haven't had the time or inclination to worry much about that (beyond the basic 'it starts without drama when its cold'.
I'm pretty sure (but not absolutely) that Bosch LH is firing multiple times over the course of all 4 cylinders firing, even though all 4 cylinders get spritzed at the same time. I think it's 4 times per 2 rotations, though, maybe 2? So all 4 cylinders get the same pattern of spritzes - 3 on a closed valve, 1 on an open valve (or very close to it).